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Chemistry · Unit 3 · Chemical equilibrium systems · Chemical equilibrium

Analyse data to determine reaction quotients (Q), equilibrium constants (Kc), the concentrations of reactants and products and the concentration of ions in aqueous solutions. Properties of acids and bases

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Question 1

A chemist prepares a solution by dissolving sodium hydroxide (NaOH) in water. The hydroxide ion concentration is measured as \(2.50 \times 10^{-3}\) mol L\(^{-1}\) at 298 K. Analyse the data to determine the hydrogen ion concentration, \([\text{H}^{+}]\), in the solution.

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Question 2

A weak acid, HA, has an acid dissociation constant \(K_a = 1.8 \times 10^{-5}\) at 298 K. A solution of this acid is prepared with an equilibrium hydronium ion concentration of \([\text{H}_3\text{O}^+] = 4.0 \times 10^{-3}\) mol L\(^{-1}\) and an equilibrium conjugate base concentration of \([\text{A}^-] = 4.0 \times 10^{-3}\) mol L\(^{-1}\). Analyse the data to determine: (a) the equilibrium concentration of the undissociated acid, \([\text{HA}]\) (b) the pH of the solution.

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Question 3

A weak acid, HA, has an acid dissociation constant (\(K_a\)) of \(1.8 \times 10^{-5}\). At equilibrium, an aqueous solution of HA has a hydronium ion concentration of \(3.0 \times 10^{-3}\) mol L\(^{-1}\) and a conjugate base concentration of \(3.0 \times 10^{-3}\) mol L\(^{-1}\). Analyse the data to determine the equilibrium concentration of the undissociated acid HA.

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